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Stereoselective Preparation of Highly Functionalized (Z)-3-Copper Enoates by an Iodine—Copper Exchange Reaction.

✍ Scribed by Xiaoyin Yang; Paul Knochel


Publisher
John Wiley and Sons
Year
2006
Weight
27 KB
Volume
37
Category
Article
ISSN
0931-7597

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✍ Laure Boymond; Mario Rottländer; Gérard Cahiez; Paul Knochel 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 107 KB 👁 2 views

At -40°C aryl iodides that contain other functional groups can be selectively converted into Grignard reagents, which react with electrophiles such as benzaldehyde in the usual manner [Eq. (a)]. Aryl bromides and iodides that are immobilized as esters on a Wang resin behave analogously.