By using relative rate methods, rate constants for the gas-phase reactions of OH and NO 3 radicals with propanal, butanal, pentanal, and hexanal have been measured at 296 ฯฎ 2 K and atmospheric pressure of air. By using methyl vinyl ketone as the reference compound, the rate constants obtained for th
Prediction of rate constants for the gas phase reactions of triphenylene with OH and NO3 radicals using a relative rate method in CCl4 liquid phase-system
โ Scribed by Takayuki Kameda; Koji Inazu; Kohei Asano; Madoka Murota; Norimichi Takenaka; Yasuhiro Sadanaga; Yoshiharu Hisamatsu; Hiroshi Bandow
- Book ID
- 118429452
- Publisher
- Elsevier Science
- Year
- 2013
- Tongue
- English
- Weight
- 311 KB
- Volume
- 90
- Category
- Article
- ISSN
- 0045-6535
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๐ SIMILAR VOLUMES
Using a relative rate method, rate constants for the gas-phase reactions of 2methyl-3-buten-2-ol (MBO) with OH radicals, ozone, NO 3 radicals, and Cl atoms have been investigated using FTIR. The measured values for MBO at and total 298 ฯฎ 2 K 740 ฯฎ 5 torr pressure are: ฯช11 3 ฯช1 ฯช1 ฯช18 3 k ฯญ (3.9 ฯฎ 1.
The homogeneous gas-phase reaction of NzH4 with O3 in air at atmospheric pressure has been used to generate OH radicals in the dark, allowing the determination of relative OH radical rate constants for compounds which photolyze rapidly. This technique was first validated by determining the OH radica