The equilibrium between hydrogen-methane gas mixtures and Fe-Si-C solid solutions has been investigated both as 8 function of temnerature and carburizinn 1~8s comnosition. The ihermodynamic properties of the carbon atoms in b0th"byc.c. and f.c.c. solid solution have been derived from the equilibriu
Precipitation out of dual solid solutions of carbon and nitrogen in alpha-iron
β Scribed by C Wert
- Publisher
- Elsevier Science
- Year
- 1954
- Weight
- 762 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0001-6160
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β¦ Synopsis
The problem of precipitation in dual solid solutions of C and Ns in a-iron was examined experimentally. The internal friction of these solutions was found to be a useful property with which to study this change of phase. The effect of either of these elements is to speed up the aging of the one with the slower rate to equal that of the faster. This is interpreted to be an effect of easier nucleation. The structure of the precipitate resulting from aging of this dual solution is unknown. Magnetic coercive force measurements have been made during aging; these are more difficult to interpret than internal friction data. This is thought to be caused by a pronounced particle size effect on the coercive force. LA PRECIPITATION A PARTIR DE SOLUTIONS SOLIDES, DOUBLES DE C ET DE NP DANS LE FER-a On a examin exp&imentalement le probleme de precipitation B partir des solutions solides, doubles de C et de Ns dans le fer-ol. Dans I'Ctude du changement des phases il est avantageux de se servir du frottement interne de ces solutions solides comme propri& indicative. L'effet de chacun de ces elements est d'acc&rer le vieillissement de l'eldment dont la vitesse est plus faible, jusqu'a ce qu'il atteigne la vitesse de l'&ment le plus rapide. Ceci est interpr&C comme &ant un effet de germination plus facile. La structure du pr6cipit6 qui apparait au vieillissement de cette solution double est inconnue. On a mesure la force coercitive, magnCtique pendant le vieillissement; il est, toutefois, plus difficile d'interprbter ces r&ultats que les donnees obtenues par la mesure du frottement interne. On suppose que cette difficult6 est causee par l'effet important des dimensions des grains sur la force coercitive. AUSSCHEIDUNGEN VON ZWEIFACH FESTEN LOSUNGEN VON C UND Nz IN a-EISEN Das Problem der Ausscheidune aus zweifach festen Losuneen von C und Nt in a-Eisen wurde experimentell untersucht. Es zeig?e sich, dass die innere ReibuGg dieser Lijsungen eine zum Studium dieser Phasenumwandlung gut geeignete Eigenschaft ist. Jedes der Losungselemente hat folgende Wirkung: Es beschleunigt das Altern des Elements mit der geringeren Alterungsgeschwindigkeit urn diese der des schneller alternden Elementes anzugleichen. Diese Erscheinung wird als ein Effekt der leichteren Keimbildung erkllrt. Die Struktur der beim Altern dieser zweifachen Losung auftretenden Ausscheidung ist nicht bekannt. WLhrend der Ausscheidung wurden Messungen der magnetischen Koerzitivkraft durchgefiihrt. Sie sind schwieriger zu interpretieren als die Werte der inneren Reibung. Ein starker Effekt der Teilchengrosse auf die Koerzitivkraft wird als Grund daftir angesehen. *At 1 cps, the nitrogen peak occurs at 22"C, the carbon peak at 40Β°C. The contribution of each peak at the temperature of the other is seen from Figure 2 to be some 35 per cent.
ACTA
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