The title compound, [Cu(SCN)(C~3~H~5~NS~2~)]~__n__~, was prepared from the direct reaction between copper(I) thiocyanate and 1,3-thiazolidine-2-thione. The structure is an infinite two-dimensional polymer, parallel to the __ac__ plane, with tetrahedrally distorted Cu atoms which are coordinated by t
Poly[μ3-1,3-dithiolane-2-methanol-κ3S:S:S′-μ-nitrato-silver(I)]
✍ Scribed by Zhang, Hongming ;Gondi, Sudershan R. ;Son, David Y.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 255 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, {[Ag(C 15 H 16 S 2 ) 2 ]SbF 6 Á0.5C 4 H 10 O} n , was obtained from the self-assembly of AgSbF 6 and 1,3-bis-(phenylsulfanyl)propane. Each Ag I ion is coordinated by four S atoms from different ligands, forming a distorted tethrahedral geometry. Each ligand links adjacent Ag I io
Single-crystal X-ray study T = 294 K Mean (C-C) = 0.012 A R factor = 0.037 wR factor = 0.078 Data-to-parameter ratio = 12.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the crystal structure of the title compound, [Cu(NCS)-(C 4 H 3 IN 2 )] n , each Cu atom is coordinated by three thiocyanate anions and one 2-iodopyrazine ligand within a distorted tetrahedron. The Cu-coordinated units form dimers, which are connected into layers by the thiocyanate anions.