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Poly[[bis[μ2-1,3-bis(phenylsulfanyl)propane-κ2S:S′]silver(I)] hexafluoridoantimonate diethyl ether hemisolvate]

✍ Scribed by Awaleh, Mohamed Osman ;Badia, Antonnella ;Brisse, François

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 778 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807056371

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✦ Synopsis

The title compound, {[Ag(C 15 H 16 S 2 ) 2 ]SbF 6 Á0.5C 4 H 10 O} n , was obtained from the self-assembly of AgSbF 6 and 1,3-bis-(phenylsulfanyl)propane. Each Ag I ion is coordinated by four S atoms from different ligands, forming a distorted tethrahedral geometry. Each ligand links adjacent Ag I ions, forming an extended two-dimensional grid-like framework. SbF 6 À ions, which are incorporated into the cavities of the network, complete and stabilize the structure. One of the phenyl rings is disordered over two sites, the ratio of occupancies being

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