Polymerization of monomers containing thiiran rings
β Scribed by Rogers, F. E.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1965
- Tongue
- English
- Weight
- 187 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0449-2951
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π SIMILAR VOLUMES
## Abstract Ring polymers are synthesized using a cyclic bifunctional thioester as initiator for REP of thiiranes. PMT yields satisfactory results, whereas polymerization with MT appears to develop dead polymeric material as byβproduct and TBMT gives only negligible conversion rates. The process pr
Stereospecific polymerizations of racemic mixtures of chiral cyclic monomers have been shown to be stereoselective with non chiral initiators and stereoelective with some chiral initiators. The bulkiness of the ring substituents influences the interaction of monomer with initiator and this leads to
## Abstract The synthesis and polymerization of fusedβring 1,7βdidodecylβ1,7βdihydrothieno[3,2β__b__:4,5β__bβ²__]dipyrrole monomer are reported. The FeCl~3~βmediated oxidative polymerization and Stille coupling polymerization of the thienodipyrrole monomer were employed to generate homopolymers and