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Synthesis and Polymerization of Fused-Ring Thienodipyrrole Monomers

✍ Scribed by Hien Q. Nguyen; Elizabeth A. Rainbolt; Prakash Sista; Mihaela C. Stefan

Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
780 KB
Volume
213
Category
Article
ISSN
1022-1352

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✦ Synopsis

Abstract

The synthesis and polymerization of fused‐ring 1,7‐didodecyl‐1,7‐dihydrothieno[3,2‐b:4,5‐b′]dipyrrole monomer are reported. The FeCl~3~‐mediated oxidative polymerization and Stille coupling polymerization of the thienodipyrrole monomer were employed to generate homopolymers and an alternating copolymer with thiophene. The synthesized polymers have molecular weights ranging from 1600 to 6500 g mol^−1^ and display the absorption maxima at ≈355 nm.

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