Ring-opening polymerization of nitrogen-containing cyclic organosilicon monomers
β Scribed by M. Bouquey; C. Brochon; S. Bruzaud; A-F. Mingotaud; M. Schappacher; A. Soum
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 783 KB
- Volume
- 521
- Category
- Article
- ISSN
- 0022-328X
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## Abstract The Ring Opening Metathesis Polymerization (ROMP) of a series of cyclic alkenes bearing heteroatom functionality has been performed using a classical WCl~6~βbased catalyst system. All of the alkenes studied exhibited significantly slower polymerization rates compared with the hydrocarbo
Stereospecific polymerizations of racemic mixtures of chiral cyclic monomers have been shown to be stereoselective with non chiral initiators and stereoelective with some chiral initiators. The bulkiness of the ring substituents influences the interaction of monomer with initiator and this leads to
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