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Polymerization of methyl methacrylate with aminoalcohols and carbon tetrachloride initiated by charge-transfer mechanism

✍ Scribed by P. C. Dwivedi; S. D. Pandey; A. Tandon; S. Singh


Publisher
Springer
Year
1995
Weight
403 KB
Volume
273
Category
Article
ISSN
0340-255X

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The kinetics of charge-transfer (CT) polymerization of methyl methacrylate (MMA) in the presence of imidazole (Imy) and CCI, was studied in dimethyl sulfoxide (DMSO) at 60Β°C. The rate of polymerization (R,) is sensitive t o the [CCl,] up to a concentration of 0.60 mol L-I, but at a higher concentrat

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Methyl methacrylate (MMA) can be polymerized by the charge-transfer complex formed by the interaction of melamine (MM), MMA and carbon tetrachloride in a non-aqueous solvent like dimethyl sulphoxide (DMSO) or N-N-dimethylformamide. The polymerization can be accelerated by Lewis acids like Fe 3+. Thi