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Polymerization of methyl methacrylate by a charge transfer mechanism with urea and iron (III) complex

โœ Scribed by Hussain, S. ;Dass, N. N.


Publisher
John Wiley and Sons
Year
1982
Weight
302 KB
Volume
20
Category
Article
ISSN
0360-6376

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Polymerization of methyl methacrylate by
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Methyl methacrylate (MMA) can be polymerized by the charge-transfer complex formed by the interaction of melamine (MM), MMA and carbon tetrachloride in a non-aqueous solvent like dimethyl sulphoxide (DMSO) or N-N-dimethylformamide. The polymerization can be accelerated by Lewis acids like Fe 3+. Thi

Polymerization of methyl methacrylate by
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Polymerization of methyl methacrylate (MMA) by the charge-transfer complex formed by the interaction of 2,2-bipyridine (bpy), MMA, and carbon tetrachloride (CCl 4 ) was studied in dimethylsulfoxide (DMSO) at 60ะŠC. The rate of polymerization (R p ) is sensitive to the [CCl 4 ] at low concentration of

Mechanism of polymerization of methyl me
โœ A. Dutta; P.K. Mahato; N.N. Dass ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 336 KB

The triphenylphosphine (TPP) initiated polymerization of methyl methacrylate (MMA) in dimethyl sulphoxide (DMSO) has been studied. The polymerization was found to be solvent-sensitive and could be accelerated by Lewis acids like Fe 3รท . Kinetic studies showed that the propagation was free radical in

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โœ Shashi D. Baruah ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 455 KB ๐Ÿ‘ 2 views

## Abstract The effect of the Lewis acid, iron(III) tris(oxalato)ferrate(III) tetrahydrate (Feโ€[Fe(C~2~O~4~)~3~].4H~2~O) (A) on the polymerization of butyl methacrylate (BuMA) initiated by a chargeโ€transfer mechanism has been studied in dimethyl sulfoxide (DMSO) at 60ยฐC. 2,4โ€dinitrophenylhydrazine