Charge transfer polymerization of 2-vinyl pyridine initiated by n-butyl amine and carbon tetrachloride
β Scribed by Gogoi, A. K. ;Dass, N. N.
- Publisher
- John Wiley and Sons
- Year
- 1983
- Weight
- 314 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0360-6376
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The kinetics of charge-transfer (CT) polymerization of methyl methacrylate (MMA) in the presence of imidazole (Imy) and CCI, was studied in dimethyl sulfoxide (DMSO) at 60Β°C. The rate of polymerization (R,) is sensitive t o the [CCl,] up to a concentration of 0.60 mol L-I, but at a higher concentrat
Ruthenium trichloride (RuCl 3 or Ru III ) catalyzed polymerization of methylmethacrylate (MMA) initiated with n-butylamine (BA) in the presence of carbon tetrachloride (CCl 4 ) by a charge-transfer mechanism has been investigated in a dimethylsulfoxide (DMSO) medium by employing a dilatometric techn