The kinetics of charge-transfer (CT) polymerization of methyl methacrylate (MMA) in the presence of imidazole (Imy) and CCI, was studied in dimethyl sulfoxide (DMSO) at 60°C. The rate of polymerization (R,) is sensitive t o the [CCl,] up to a concentration of 0.60 mol L-I, but at a higher concentrat
Kinetics and mechanism of the charge-transfer polymerization of methyl methacrylate initiated with n-butyl amine and carbon tetrachloride catalyzed by palladium dichloride
✍ Scribed by Rajesh Tiwari; David A. Spivak
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 828 KB
- Volume
- 124
- Category
- Article
- ISSN
- 0021-8995
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Ruthenium trichloride (RuCl 3 or Ru III ) catalyzed polymerization of methylmethacrylate (MMA) initiated with n-butylamine (BA) in the presence of carbon tetrachloride (CCl 4 ) by a charge-transfer mechanism has been investigated in a dimethylsulfoxide (DMSO) medium by employing a dilatometric techn
## Abstract The effect of the Lewis acid, iron(III) tris(oxalato)ferrate(III) tetrahydrate (Fe‐[Fe(C~2~O~4~)~3~].4H~2~O) (A) on the polymerization of butyl methacrylate (BuMA) initiated by a charge‐transfer mechanism has been studied in dimethyl sulfoxide (DMSO) at 60°C. 2,4‐dinitrophenylhydrazine