Polymerization of hexafluoro-1,3-butadiene
β Scribed by V. V. Korshak; A. M. Polyakova; M. D. Suchkova
- Book ID
- 112436288
- Publisher
- Springer
- Year
- 1959
- Tongue
- English
- Weight
- 309 KB
- Volume
- 8
- Category
- Article
- ISSN
- 1573-9171
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## Abstract Initiation and propagation reaction mechanisms of the anionic polymerization of hexafluoroβ1,3βbutadiene (HEBD) were investigated. The initiation reaction with caesium tertβbutoxide was found to be completed within 5 min although the reactions were carried out at a much lower temperatur
Two distinct radical cations have been observed by ESR in a-y-irradiated solid solution of hexafluoro-1,3-butadienc in freon. INDO calculations of ESR parameters showed that they were the cisoid CC& and tiansoid (Gh) forms of the planar hesafluoroburadicne radical cation. The unpaired electron occup