Microemulsion polymerization of 1,3-butadiene
✍ Scribed by O. Robles-Vásquez; F. Moscoso-Sánchez; F. López-Serrano; M. Arellano; A. González-Álvarez; E. Mendizábal; J. E. Puig
- Publisher
- Springer
- Year
- 2010
- Tongue
- English
- Weight
- 232 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0170-0839
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The ternary neodymium-based catalyst for the polymerization of 1,3butadiene, Nd(versatate),/AliBu,H/tert-butyl chloride, has been examined with respect to the effects of replacing the alkylaluminium hydride with aluminoxane, namely methylaluminoxane (MAO) and tetraisobutyldialuminoxane (TIBAO). Cata
ln order to adapt the reduction-activation reaction of hydrogen peroxide to the polymerization of 2-phenyl-l,3-butadiene, emulsion polymerization was carried out with H202/Fe 2+ as catalyst in the presence of sodium pyrophosphate. The influences of emulsifier, iron ligand, electrolyte salt and polym