Anionic polymerization of 1-ferrocenyl-1,3-butadiene
β Scribed by Van Landuyt, Dennis C.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1972
- Tongue
- English
- Weight
- 164 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0449-2986
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π SIMILAR VOLUMES
## Abstract Initiation and propagation reaction mechanisms of the anionic polymerization of hexafluoroβ1,3βbutadiene (HEBD) were investigated. The initiation reaction with caesium tertβbutoxide was found to be completed within 5 min although the reactions were carried out at a much lower temperatur
The anionic polymerization of 1,3-butadiene using a novel metalloidal anion initiator, triallylstannyllithium (TALi)-allyllithium ( ALi), was studied. The TALi-ALi initiated anionic polymerization of 1,3-butadiene gave the star polymer along with the linear polybutadiene (PBD). The star polymer cons