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Anionic polymerization of hexafluoro-1,3-butadiene

✍ Scribed by T. Narita


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
55 KB
Volume
54
Category
Article
ISSN
0022-1139

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Anionic polymerization of fluorine-conta
✍ Shin Nishimura; Akio Takahashi; Tadashi Narita; Tokio Hagiwara; Hiroshi Hamana πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 471 KB

## Abstract Initiation and propagation reaction mechanisms of the anionic polymerization of hexafluoro‐1,3‐butadiene (HEBD) were investigated. The initiation reaction with caesium tert‐butoxide was found to be completed within 5 min although the reactions were carried out at a much lower temperatur

The radical cation of hexafluoro-1,3-but
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Two distinct radical cations have been observed by ESR in a-y-irradiated solid solution of hexafluoro-1,3-butadienc in freon. INDO calculations of ESR parameters showed that they were the cisoid CC& and tiansoid (Gh) forms of the planar hesafluoroburadicne radical cation. The unpaired electron occup