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The radical cation of hexafluoro-1,3-butadiene: An ESR study

✍ Scribed by M. Shiotani; H. Kawazoe; J. Sohma

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 401 KB
Volume: 111
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)85501-3

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✦ Synopsis

Two distinct radical cations have been observed by ESR in a-y-irradiated solid solution of hexafluoro-1,3-butadienc in freon. INDO calculations of ESR parameters showed that they were the cisoid CC& and tiansoid (Gh) forms of the planar hesafluoroburadicne radical cation. The unpaired electron occupies a s-type orbital of a2 symmetry in Cqv and bg szmmclry in CHID_

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