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Formation of methylpropargyl radicals from tetramethylcyclobutadiene radical cations: an esr study

✍ Scribed by Katsutoshi Ohta; Masaru Shiotani; Junkichi Sohma; Akinori Hasegawa; Martyn C.R. Symons


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
574 KB
Volume
136
Category
Article
ISSN
0009-2614

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✦ Synopsis


Exposure of dilute solutions of CH,C=CCH3 in CCI,FCCIF2 and related solvents to ionizing radiation at 77 K produced the radical cation (CH3C=CCH3 )'. On annealing, these were initially converted into the corresponding dimer cation, c-C,( CH,


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