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The triethylenediamine cation radical: An ESR study

✍ Scribed by George W. Eastland; Martyn C.R. Symons

Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 90 KB
Volume: 45
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(77)80053-5

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✦ Synopsis

Compared with normal and bridge-head aminium cations, the i.riethylenediamine cation is relatively stable. Its ESR specffum shows that the wo nitrogen atoms and all the protons are magnetically equivalent even at 77 K. This f&ours a symmetrical ground state rather than a dynamic equilibrium between classical, asymmetric structures.

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