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Poly[diaqua-μ4-benzene-1,4-dicarboxyl­ato-di-μ2-benzene-1,4-dicarboxyl­ato-bis­(N,N′-dimethyl­formamide)digadolinium(III)]

✍ Scribed by Zhang, Wen-Zhi

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
284 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Gd~2~(C~8~H~4~O~4~)~3~(C~3~H~7~NO)~2~(H~2~O)~2~]~n~, the central Gd^III^ atom is nine-coordinated by seven O atoms from benzene-1,4-dicarboxylate (1,4-BDC) ligands, one dimethylformamide and one water molecule in a distorted tricapped trigonal–prism coordination. The 1,4-BDC ligands link the Gd^III^ atoms, forming a three-dimensional structure. All aromatic rings are located on centres of inversion. The water molecule forms hydrogen bonds to carboxylate groups.

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