In the title compound, [Gd~2~(C~8~H~4~O~4~)~3~(C~3~H~7~NO)~2~(H~2~O)~2~]~__n__~, the central Gd^III^ atom is nine-coordinated by seven O atoms from benzene-1,4-dicarboxylate (1,4-BDC) ligands, one dimethylformamide and one water molecule in a distorted tricapped trigonal–prism coordination. The 1,4-
A gadolinium-based metal–organic framework, poly[[tris(μ4-benzene-1,4-dicarboxylato)bis(μ2-N,N-diethylformamide)digadolinium(III)] monohydrate]
✍ Scribed by Poulsen, Rasmus D. ;Overgaard, Jacob ;Chevallier, Marie-Agnes ;Clausen, Henrik F. ;Iversen, Bo B.
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 406 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
A gadolinium-based metal-organic framework, poly[[tris(l 4 -benzene-1,4-dicarboxylato)bis(l 2 -N,N-diethylformamide)digadolinium(III)] monohydrate]
📜 SIMILAR VOLUMES
An Eu-based metal-organic framework: poly[[tris-(l 4 -benzene-1,4-dicarboxylato)bis(l 2 -N,N-diethylformamide)dieuropium(III)] 0.7-hydrate]
Single-crystal X-ray study T = 294 K Mean (C-C) = 0.004 A R factor = 0.044 wR factor = 0.125 Data-to-parameter ratio = 15.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.