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catena-Poly[[[μ-benzene-1,4-dicarboxyl­ato-bis­[tetra­aqua­lutetium(III)]]-di-μ-benzene-1,4-dicarboxyl­ato] dihydrate]

✍ Scribed by Wang, Ping ;Li, Zhi-Feng ;Song, Le-Ping ;Wang, Chun-Xiang ;Chen, Ying

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
212 KB
Volume
62
Category
Article
ISSN
1600-5368

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✍ Zhang, Wen-Zhi 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 284 KB

In the title compound, [Gd~2~(C~8~H~4~O~4~)~3~(C~3~H~7~NO)~2~(H~2~O)~2~]~__n__~, the central Gd^III^ atom is nine-coordinated by seven O atoms from benzene-1,4-dicarboxylate (1,4-BDC) ligands, one dimethylformamide and one water molecule in a distorted tricapped trigonal–prism coordination. The 1,4-

catena-Poly[[dimethyl­tin(IV)]-μ-benzene
catena-Poly[[dimethyl­tin(IV)]-μ-benzene-1,4-dicarboxyl­ato]
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In the title compound, [Sn(CH 3 ) 2 (C 8 H 4 O 4 )], the coordination geometry around the Sn IV centre can be described as highly distorted octahedral. The chelating benzene-1,4-dicarboxylate ligands connect the centres to form an infinite one-dimensional polymeric chain structure.