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Polycaprolactone-Based Novel Degradable Ionomers by Radical Ring-Opening Polymerization of 2-Methylene-1,3-dioxepane

✍ Scribed by Seema, Agarwal; Liqun, Ren

Book ID
126297058
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
668 KB
Volume
42
Category
Article
ISSN
0024-9297

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Synthesis of poly-ε-caprolactone via a free radical mechanism. Free radical ring-opening polymerization of 2-methylene-1,3-dioxepane
✍ Bailey, William J. ;Ni, Zhende ;Wu, Shang-Ren 📂 Article 📅 1982 🏛 John Wiley and Sons ⚖ 405 KB

## Abstract 2‐Methylene‐1,3‐dioxepane 6 polymerized with a quantitative ring opening to form poly‐ϵ‐caprolactone via a free radical mechanism. On the other hand, 2‐methylene‐1,3‐dioxolane (ethylene ketene acetal) 4 and 2‐methylene‐1,3‐dioxane 5, under the same conditions, generated polymers with mi