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A Study of the Mechanism of the Free-Radical Ring-Opening Polymerization of 2-Methylene-1,3-dioxepane

✍ Scribed by Jin, S.; Gonsalves, K. E.

Book ID
120628341
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
162 KB
Volume
30
Category
Article
ISSN
0024-9297

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✍ Bailey, William J. ;Ni, Zhende ;Wu, Shang-Ren 📂 Article 📅 1982 🏛 John Wiley and Sons ⚖ 405 KB

## Abstract 2‐Methylene‐1,3‐dioxepane 6 polymerized with a quantitative ring opening to form poly‐ϵ‐caprolactone via a free radical mechanism. On the other hand, 2‐methylene‐1,3‐dioxolane (ethylene ketene acetal) 4 and 2‐methylene‐1,3‐dioxane 5, under the same conditions, generated polymers with mi