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“Living” Free Radical Ring-Opening Polymerization of 5,6-Benzo-2-methylene-1,3-dioxepane Using the Atom Transfer Radical Polymerization Method

✍ Scribed by Yuan, Jin-Ying; Pan, Cai-Yuan; Tang, Ben Zhong

Book ID
126167343
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
56 KB
Volume
34
Category
Article
ISSN
0024-9297

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Synthesis of poly-ε-caprolactone via a free radical mechanism. Free radical ring-opening polymerization of 2-methylene-1,3-dioxepane
✍ Bailey, William J. ;Ni, Zhende ;Wu, Shang-Ren 📂 Article 📅 1982 🏛 John Wiley and Sons ⚖ 405 KB

## Abstract 2‐Methylene‐1,3‐dioxepane 6 polymerized with a quantitative ring opening to form poly‐ϵ‐caprolactone via a free radical mechanism. On the other hand, 2‐methylene‐1,3‐dioxolane (ethylene ketene acetal) 4 and 2‐methylene‐1,3‐dioxane 5, under the same conditions, generated polymers with mi