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Poly[[aqua­bis(μ-benzene-1,3-dicarboxyl­ato)bis­(μ-3-carboxy­benzoato)digadolinium(III)] monohydrate]

✍ Scribed by Lu, Ji-Lin ;Zhang, Da-Shun ;Liu, Bei-Ping

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
267 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Gd 2 (C 8 H 4 O 4 ) 2 (C 8 H 5 O 4 ) 2 (H 2 O)]ÁH 2 O, the Gd III ions are nine-coordinated and linked by carboxylate O bridges, giving rise to right-and left-handed inorganic helical chains. The crystal structure is stabilized by intra-and intermolecular O-HÁ Á ÁO hydrogen bonds, linking the chains into a three-dimensional framework.

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