The title compound, [Zn(C~10~H~8~O~5~)(C~12~H~8~N~2~)(H~2~O)~3~], is a neutral mononuclear complex. The Zn atom has a distorted octahedral geometry involving one O atom of the 3-(4-carboxylatophenoxy)propionate group, two N atoms of the 1,10-phenanthroline ligand and three water molecules. Extensive
Poly[[(1,10-phenanthroline)cadmium(II)]-μ3-2-(4-carboxylatophenoxy)propionato]
✍ Scribed by Kong, Li-Li ;Gao, Shan ;Huo, Li-Hua
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 801 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title linear polymeric chain compound, [Cd(C~10~H~8~O~5~)(C~12~H~8~N~2~)]~n~, the Cd^II^ ion exists in a monocapped triangular–prismatic geometry that is defined by two N atoms from a 1,10-phenanthroline molecule and five O atoms from three 2-(4-carboxylatophenoxy)propionate ligands. Adjacent chains are cross-linked via π–π stacking interactions between the 1,10-phenanthroline rings [centroid–centroid distance = 3.5894 (6) Å].
📜 SIMILAR VOLUMES
The zwitterionic title compound, [Mn(C 10 H 8 O 5 )(C 12 H 8 N 2 )-(H 2 O) 3 ]ÁH 2 O, has the Mn atom in an octahedral geometry that comprises the O atom of the 2-(4-carboxylatophenoxy)propionate group, two N atoms of the 1,10-phenanthroline ligand and three water molecules. Extensive hydrogenbondin
Single-crystal X-ray study T = 223 K Mean '(C±C) = 0.012 A Ê R factor = 0.067 wR factor = 0.159 Data-to-parameter ratio = 18.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, {[Co(C~8~H~3~BrO~4~)(C~12~H~8~N~2~)(H~2~O)]·H~2~O}~__n__~, each Co^II^ ion is six-coordinated by three O atoms from three carboxylate groups of three 4-bromoisophthalate dianions, one water molecule, and two N atoms from a 1,10-phenanthroline ligand. The coordination geometry
In the crystal structure of the polymeric title compound, [Mn(C~10~H~8~N~2~)(C~10~H~8~O~5~)(H~2~O)]~__n__~, the Mn^II^ atom is __O__,__O__′-chelated by the aromatic carboxylate end of the 3-(4-carboxylatophenoxy)propionate dianion and is covalently bonded (through one O atom) by the aliphatic carbox
In the crystal structure of the polymeric title compound, [Co(C~10~H~8~O~5~)(C~10~H~8~N~2~)(H~2~O)]~__n__~, the Co^II^ atom is __O__,__O__′-chelated by the aromatic carboxylate end of the 3-(4-carboxylatophenoxy)propionate dianion, and is covalently bonded (through one O atom) by the aliphatic carbo