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Poly[[(1,10-phenanthroline)cadmium(II)]-μ3-2-(4-carboxylatophenoxy)propionato]

✍ Scribed by Kong, Li-Li ;Gao, Shan ;Huo, Li-Hua


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
801 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title linear polymeric chain compound, [Cd(C~10~H~8~O~5~)(C~12~H~8~N~2~)]~n~, the Cd^II^ ion exists in a monocapped triangular–prismatic geometry that is defined by two N atoms from a 1,10-phenanthroline molecule and five O atoms from three 2-(4-carboxylatophenoxy)propionate ligands. Adjacent chains are cross-linked via π–π stacking interactions between the 1,10-phenanthroline rings [centroid–centroid distance = 3.5894 (6) Å].


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In the crystal structure of the polymeric title compound, [Mn(C~10~H~8~N~2~)(C~10~H~8~O~5~)(H~2~O)]~__n__~, the Mn^II^ atom is __O__,__O__′-chelated by the aromatic carboxylate end of the 3-(4-carboxylatophenoxy)propionate dianion and is covalently bonded (through one O atom) by the aliphatic carbox

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