Platinum-catalyst-assisted metalorganic vapor phase epitaxy of InN

✍ Scribed by Kohei Sasamoto; Ken-ichi Sugita; Akihiro Hashimoto; Akio Yamamoto

• Book ID: 104022077
• Publisher: Elsevier Science
• Year: 2011
• Tongue: English
• Weight: 329 KB
• Volume: 314
• Category: Article
• ISSN: 0022-0248
• DOI: 10.1016/j.jcrysgro.2010.10.064

✦ Synopsis

This paper reports the first attempt of the Pt-catalyst-assisted MOVPE growth of InN. In order to enhance NH 3 decomposition at a relatively low growth temperature ($ 550 1C), Pt is used as a catalyst. The catalyst is installed in the NH 3 introduction tube in the MOVPE reactor and the tube is located just above the susceptor to be heated. Compared with InN films grown without the catalyst, the samples grown with Pt catalyst show improved electrical properties; a carrier concentration in the order of 10 18 cm À 3 and a Hall mobility as high as 1350 cm 2 /Vs are obtained. The crystalline quality is also improved by employing the catalyst and a tilt fluctuation as low as 8.6 arcmin is obtained for a sample grown on a GaN/sapphire template. It is confirmed that for InN films grown at 550 1C with Pt catalyst, the electrical and crystallographic properties are also improved with increase in thickness. These results indicate that the growth at around 550 1C with the Pt catalyst is performed under the circumstances where NH 3 is effectively decomposed, whereas the deterioration of InN during growth is significantly suppressed.