In the title compound, (C 4 H 12 N 2 )[Ti(C 7 H 4 O 3 ) 3 ]ÁH 2 OÁ-C 3 H 7 NO, the Ti IV atom is chelated by three salicylate ligands in an octahedral geometry, the complex anion being the fac isomer. The cations, complex anions and solvent molecules are linked by hydrogen bonds into a layer structu
Piperazinium fac-tris(salicylato-κ2O,O′)titanate(IV) dimethylformamide solvate
✍ Scribed by Ren, Jia-Lin ;Fu, Yun-Long ;Xu, Zhi-Wei
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 203 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, (C 2 H 8 N) 2 [Ti(C 7 H 4 O 3 ) 3 ], the Ti IV atom is chelated by three salicylate ligands in a mer-octahedral geometry. The cations and complex anions are linked by hydrogen bonds into a layer structure.
catena-Poly[hemi[diaquacopper(II) ]-l-salicylato-
Single-crystal X-ray study T = 294 K Mean (C-C) = 0.004 A R factor = 0.044 wR factor = 0.125 Data-to-parameter ratio = 15.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, [Zn(C~7~H~4~O~5~S)(C~13~H~14~N~2~)(H~2~O)~2~]·C~3~H~7~NO, the Zn^II^ atom is coordinated by two N atoms from two 1,3-di-4-pyridylpropane molecules, two O atoms from one 2-sulfonatobenzoate dianion and two aqua O atoms, in a distorted octahedral geometry. The 2-sulfonatobenzoat