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Piperazinium(2+) fac-tris­(salicylato-κ2O,O′)titanate(IV) monohydrate dimethyl­formamide solvate

✍ Scribed by Fu, Yun-Long ;Xu, Zhi-Wei ;Ren, Jia-Lin ;Ng, Seik Weng

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
212 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, (C 4 H 12 N 2 )[Ti(C 7 H 4 O 3 ) 3 ]ÁH 2 OÁ-C 3 H 7 NO, the Ti IV atom is chelated by three salicylate ligands in an octahedral geometry, the complex anion being the fac isomer. The cations, complex anions and solvent molecules are linked by hydrogen bonds into a layer structure.

📜 SIMILAR VOLUMES

Bis(dimethyl­ammonium) mer-tris­(salicyl
Bis(dimethyl­ammonium) mer-tris­(salicylato-κ2O,O′)titanate(IV)
✍ Fu, Yun-Long ;Xu, Zhi-Wei ;Ren, Jia-Lin ;Ng, Seik Weng 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 202 KB

In the title compound, (C 2 H 8 N) 2 [Ti(C 7 H 4 O 3 ) 3 ], the Ti IV atom is chelated by three salicylate ligands in a mer-octahedral geometry. The cations and complex anions are linked by hydrogen bonds into a layer structure.

catena-Poly[[[diaqua­bis(N,N-dimethyl­fo
catena-Poly[[[diaqua­bis(N,N-dimethyl­formamide)­cobalt(II)]-μ-1,4-benzene­dicarboxyl­ato-κ2O:O′] N,N-dimethyl­formamide solvate monohydrate]
✍ Jia, Chun-Xiao 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 257 KB

Single-crystal X-ray study T = 294 K Mean (C-C) = 0.004 A R factor = 0.044 wR factor = 0.125 Data-to-parameter ratio = 15.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.