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Bis(dimethyl­ammonium) mer-tris­(salicylato-κ2O,O′)titanate(IV)

✍ Scribed by Fu, Yun-Long ;Xu, Zhi-Wei ;Ren, Jia-Lin ;Ng, Seik Weng

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
202 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, (C 2 H 8 N) 2 [Ti(C 7 H 4 O 3 ) 3 ], the Ti IV atom is chelated by three salicylate ligands in a mer-octahedral geometry. The cations and complex anions are linked by hydrogen bonds into a layer structure.

📜 SIMILAR VOLUMES

Piperazinium(2+) fac-tris­(salicylato-κ2
Piperazinium(2+) fac-tris­(salicylato-κ2O,O′)titanate(IV) monohydrate dimethyl­formamide solvate
✍ Fu, Yun-Long ;Xu, Zhi-Wei ;Ren, Jia-Lin ;Ng, Seik Weng 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 212 KB

In the title compound, (C 4 H 12 N 2 )[Ti(C 7 H 4 O 3 ) 3 ]ÁH 2 OÁ-C 3 H 7 NO, the Ti IV atom is chelated by three salicylate ligands in an octahedral geometry, the complex anion being the fac isomer. The cations, complex anions and solvent molecules are linked by hydrogen bonds into a layer structu