Time-resolved in combination with steady-state experiments reveal that aromatic endoperoxides dissociate in general in IWO steps via a biradical intermediate if excited to upper xu\* singlet states. This process is not influenced by solvent. Time constants in the picosecond domain are reported.
Picosecond studies on the photodissociation dynamics of aromatic endoperoxides
β Scribed by Th. Blumenstock; K. Jesse; F.J. Comes; R. Schmidt; H.-D. Brauer
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 827 KB
- Volume
- 130
- Category
- Article
- ISSN
- 0301-0104
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