Picosecond laser studies of the photodissociation of I2—aromatic complexes and the formation of 1 atom—aromatic complexes in solution
✍ Scribed by C.A. Langhoff; K. Gnädig; K.B. Eisenthal
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 376 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0301-0104
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
A large solvent polarity effect on the rate of singlet to triplet intersystem crossing (ksT) has been observed in the carbenes, diphenylcarbene (DPC) and dicycloheptadienylidene (DCHD)-it is found that both ksT and the energy splitting (A&T) separtaing the singlet and triplet states decrease as the
A series of podands bearing phenyl, naphthyl and anthryl end groups were prepared and characterized. UV-visible spectrophotometry was used to investigate the host-guest chemistry of the podands in complexation with tropylium tetrafluoroborate in 1,2-dichloroethane. The results are discussed and comp
## Abstract Fluorescence rise and decay processes were measured and rate parameters were determined for the pyrene‐tri‐__n__‐butylamine and pyrene‐N,N‐diethylaniline exciplex system in various solvents. An additional activation energy over that for the diffusional motion appears necessary for both