✦ LIBER ✦

Picosecond photochemistry: The mechanism of photocycloreversion of aromatic endoperoxides

✍ Scribed by K. Jesse; R. Markert; F.J. Comes; R. Schmidt; H.-D. Brauer

Publisher: Elsevier Science
Year: 1990
Tongue: English
Weight: 505 KB
Volume: 166
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(90)87057-x

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✦ Synopsis

Time-resolved in combination with steady-state experiments reveal that aromatic endoperoxides dissociate in general in IWO steps via a biradical intermediate if excited to upper xu* singlet states. This process is not influenced by solvent. Time constants in the picosecond domain are reported.

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