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Picosecond study of the intersystem crossing in aromatic ketone vapors

✍ Scribed by N.A. Borisevich; Yu.I. Bubekov; G.B. Tolstorozhev; Yu. Vishchakas; V. Kabelka; A. Milyauskas

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 258 KB
Volume: 103
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)87476-4

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✦ Synopsis

An automatic laser spectrometer was used directly to measure time characteristics of triplet-triplet absorption optical density build-up in 4-phenylbenzophenone

vapor. An estimation of the intramolecular intersystem crossing rate constant is given in the picosecond time range. Differences in intramolecular intersystem crossing rate constants have been observed in 4phenylberuophenone in the condensed and gas phases.

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