✦ LIBER ✦
Picosecond and nanosecond laser studies of intersystem crossing and excited-state solvent subtitution in dibromo-1,2-bis(diphenylphosphinoethane)nickel(II)
✍ Scribed by G. Lockwood; J.J. McGarvey; R. Devonshire
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 387 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
Picosecond and nanosecond irradiation studrcs of the planar, title complcv suggest the nptd (10 ps) formation of a tqlet, tetrahedrally distorted cxcttcd state which m CH,CN undergoes tempcraturc-utdcpcndcnt attack by solvent (T -CO 91 ns) to give an ioruc species whale in CH&. trIplet -L smglct mtcrsystem crossing occurs, with k = 4 X IO's_'.