Photodesorption of carbonyl from Pt3(CO)n− (n = 1–6)
✍ Scribed by Yang Shi; Vassil A. Spasov; Kent M. Ervin
- Book ID
- 104432188
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 357 KB
- Volume
- 204
- Category
- Article
- ISSN
- 1387-3806
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📜 SIMILAR VOLUMES
A framework for the interpretation of the visihle/UV absorption spectra of high-nuclearity transition-metal cluster carbonyls based on MO studies of their electronic structure is proposed. The main characteristic of these cluster compounds is the high density of excited electronic states within a fe
## Abstract Miscellaneous tetrasubstituted ammonium salts of [Pt~3__n__~(CO)~6__n__~]^2–^ (__n__ = 5–8) clusters, obtained by the stoichiometric oxidation of the corresponding [Pt~9~(CO)~18~]^2–^ salts with tropylium tetrafluoroborate, self‐assemble into infinite semicontinuous or continuous {[Pt~3