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Electron states in [Ni3(CO)6]n2− and [Pt3(CO)6]n2−

✍ Scribed by D.W. Bullett

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
414 KB
Volume
115
Category
Article
ISSN
0009-2614

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A framework for the interpretation of the visihle/UV absorption spectra of high-nuclearity transition-metal cluster carbonyls based on MO studies of their electronic structure is proposed. The main characteristic of these cluster compounds is the high density of excited electronic states within a fe

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## Abstract Miscellaneous tetrasubstituted ammonium salts of [Pt~3__n__~(CO)~6__n__~]^2–^ (__n__ = 5–8) clusters, obtained by the stoichiometric oxidation of the corresponding [Pt~9~(CO)~18~]^2–^ salts with tropylium tetrafluoroborate, self‐assemble into infinite semicontinuous or continuous {[Pt~3