Pressure tuning spectroscopy of [Pt3(CO)6]2−n (n=3–5)
✍ Scribed by R.T. Roginski; J.R. Shapley; H.G. Drickamer; M.J. D'Aniello Jr.
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 311 KB
- Volume
- 135
- Category
- Article
- ISSN
- 0009-2614
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## Abstract Miscellaneous tetrasubstituted ammonium salts of [Pt~3__n__~(CO)~6__n__~]^2–^ (__n__ = 5–8) clusters, obtained by the stoichiometric oxidation of the corresponding [Pt~9~(CO)~18~]^2–^ salts with tropylium tetrafluoroborate, self‐assemble into infinite semicontinuous or continuous {[Pt~3
A framework for the interpretation of the visihle/UV absorption spectra of high-nuclearity transition-metal cluster carbonyls based on MO studies of their electronic structure is proposed. The main characteristic of these cluster compounds is the high density of excited electronic states within a fe