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Photochemistry of disulfides. I. Carbon-sulfur cleavage in the photosensitized decomposition of simple disulfides

✍ Scribed by Byers, Gary W.; Gruen, H.; Giles, H. G.; Schott, H. N.; Kampmeier, J. A.


Book ID
125953622
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
405 KB
Volume
94
Category
Article
ISSN
0002-7863

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A mild and rapid method was found for the reductive cleavage of the carbon-sulfur bond in the alkylthiocyanates by samarium/Cp 2 TiCl 2 system to give the corresponding dialkyl disulfides in moderate to good yields.