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The redox cleavage of the sulfur-sulfur bond and carbon-sulfur bond in organic disulfides by a model coenzyme

✍ Scribed by Chi-Hua Wang; Sheri M. Linnell; Ruth Rosenblum; Nancy Wang

Book ID
112699132
Publisher
Springer
Year
1971
Tongue
English
Weight
262 KB
Volume
27
Category
Article
ISSN
1420-682X

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A mild and rapid method was found for the reductive cleavage of the carbon-sulfur bond in the alkylthiocyanates by samarium/Cp 2 TiCl 2 system to give the corresponding dialkyl disulfides in moderate to good yields.