✦ LIBER ✦

Reductive Cleavage of the Carbon-sulfur Bond by Samarium/Cp2TiCl2 System for the Synthesis of Dialkyl Disulfides

✍ Scribed by Jia Xue-Shun; Zhang Yong-Min

Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 28 KB
Volume: 23
Category: Article
ISSN: 0256-7660
DOI: 10.1002/cjoc.200590303

No coin nor oath required. For personal study only.

✦ Synopsis

A mild and rapid method was found for the reductive cleavage of the carbon-sulfur bond in the alkylthiocyanates by samarium/Cp 2 TiCl 2 system to give the corresponding dialkyl disulfides in moderate to good yields.

📜 SIMILAR VOLUMES

Reductive Cleavage of the Carbon—Sulfur

Reductive Cleavage of the Carbon—Sulfur Bond by Samarium/Cp2TiCl2 System for the Synthesis of Dialkyl Disulfides.

✍ Xue-Shun Jia; Yong-Min Zhang 📂 Article 📅 2005 🏛 John Wiley and Sons ⚖ 13 KB

Reductive Cleavage of the Sulfur—Sulfur

Reductive Cleavage of the Sulfur—Sulfur Bond by the Samarium/Cp2TiCl2 Used for the Synthesis of S-Phenyl Thiolesters.

✍ Xueshun Jia; Yongmin Zhang 📂 Article 📅 2004 🏛 John Wiley and Sons ⚖ 72 KB 👁 1 views

ChemInform Abstract: Reduction of Arylsu

ChemInform Abstract: Reduction of Arylsulfonyl Derivatives with the Sm/Cp2TiCl2 System. A Novel Method for Preparation of Disulfides.

✍ You Huang; Hongyun Guo; Yongmin Zhang; Yulu Wang 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 1 views

ChemInform Abstract: A New Path for the

ChemInform Abstract: A New Path for the Reductive Cleavage of Te—Te Bond by the System of Cp2TiCl2/i-BuMgBr and Its Utility in Synthesis of Unsymmetrical Tellurides (III).

✍ Xian Huang; Wei-Xin Zheng 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

ChemInform Abstract: A New Method for th

ChemInform Abstract: A New Method for the Reductive Cleavage of S—S Bond by the System of Cp2TiCl2/i-BuMgBr/THF and Its Application in Synthesis of α-Alkylthio Carbonyl Compounds.

✍ Xian Huang; Wei-Xin Zheng 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 2 views

Reductive cleavage of the Se–Se bond in

Reductive cleavage of the Se–Se bond in diselenides by the Sm/HgCl2 system: Formation and reactions of samarium selenolates

✍ Lei Wang; Yongmin Zhang 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 137 KB 👁 2 views

Treatment of diaryl diselenides and dialkyl diselenides with metallic samarium and mercury (II) chloride in tetrahydrofuran conveniently gave samarium arylselenolates and alkylselenolates. These "living" species reacted with acyl chlorides, acid anhydrides, methyl chloroformate, organic halides, epo