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Redox cleavage of the sulfur-sulfur bond and carbon-sulfur bond in tetramethylthiuram disulfide by N-benzyl-1,4-dihydronicotinamide

โœ Scribed by Wang, Chi Hua; Linnell, Sheri M.; Wang, Nancy


Book ID
127258570
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
430 KB
Volume
36
Category
Article
ISSN
0022-3263

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Reductive Cleavage of the Carbon-sulfur
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A mild and rapid method was found for the reductive cleavage of the carbon-sulfur bond in the alkylthiocyanates by samarium/Cp 2 TiCl 2 system to give the corresponding dialkyl disulfides in moderate to good yields.