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Photochemistry of dibenzyl ketone

โœ Scribed by Engel, Paul S.


Book ID
126235311
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
395 KB
Volume
92
Category
Article
ISSN
0002-7863

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LVIII.?Dibenzyl ketone
โœ Young, Sydney ๐Ÿ“‚ Article ๐Ÿ“… 1891 ๐Ÿ› The Royal Society of Chemistry ๐ŸŒ English โš– 307 KB
Picosecond photodissociation of dibenzyl
โœ C. Arbour; G.H. Atkinson ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 549 KB

The primary photodissociation of dibenzyl ketone (DBK) to form the benzyl radical is examined by picosecond transient absorption (PTA) spectroscopy. This initial process precedes decarbonylation of the phenacetyl radical. Dissociation is initiated at 282 nm in solutions of methanol and cyclohexane a