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DICARBANIONS OF DIBENZYL KETONE, DIBENZYL SULFONE AND α,β,β-TRIPHENYLPROPIONITRILE

✍ Scribed by Hauser, Charles R.; Harris, Thomas M.


Book ID
126801575
Publisher
American Chemical Society
Year
1957
Tongue
English
Weight
134 KB
Volume
79
Category
Article
ISSN
0002-7863

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A synthesis of α-substituted trans-α, β-
✍ Moritani Yasunori; Ukita Tatsuzo; Nishitani Takashi; Seki Masahiko; Iwasaki Tame 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 261 KB

Substituted trans-a, /3-dibenzyl-y-butyrolactones were synthesized in a diastereoselective manner by the reaction of the potassium enolates of a, &dibenzyl-ybutyrolactones with electrophiles. The method was applied to the synthesis of (k)trachelogenin.