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A Convenient Synthesis of Dibenzyl α,α-Difluoromethyl-β-ketophosphonates

✍ Scribed by Sylvain Ladame; Michèle Willson; Jacques Périé

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
171 KB
Volume
2002
Category
Article
ISSN
1434-193X

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A synthesis of α-substituted trans-α, β-dibenzyl-γ-butyrolactones: diastereofacial differentiation in the electrophilic attack on the metal enolates of α, β-dibenzyl-γ-butyrolactones
✍ Moritani Yasunori; Ukita Tatsuzo; Nishitani Takashi; Seki Masahiko; Iwasaki Tame 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 261 KB

Substituted trans-a, /3-dibenzyl-y-butyrolactones were synthesized in a diastereoselective manner by the reaction of the potassium enolates of a, &dibenzyl-ybutyrolactones with electrophiles. The method was applied to the synthesis of (k)trachelogenin.