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A New Synthesis of α-Ketophosphonates.

✍ Scribed by Kamyar Afarinkia; Andrew Faller; Andrew J. Twist


Publisher
John Wiley and Sons
Year
2003
Weight
109 KB
Volume
34
Category
Article
ISSN
0931-7597

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Facile enolisation of α-ketophosphonates
✍ Kamyar Afarinkia; Juan Echenique; Stanley C. Nyburg 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 254 KB

A number of ¢t-ketophosphonate are prepared and shown to be easily enolised. An X-ray crystal structure determination of a ~-phenyl-ot-ketophosphonate shows the molecule to be present as hydrogen bonded dimers and demonstrates the presence of enol tautomer in solid state, ct-ketophosphonate can be