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Preparation of Dibenzyl Ketone and Phenylacetone

โœ Scribed by Hurd, Charles D.; Thomas, Charles L.


Book ID
118055080
Publisher
American Chemical Society
Year
1936
Tongue
English
Weight
103 KB
Volume
58
Category
Article
ISSN
0002-7863

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Picosecond photodissociation of dibenzyl
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The primary photodissociation of dibenzyl ketone (DBK) to form the benzyl radical is examined by picosecond transient absorption (PTA) spectroscopy. This initial process precedes decarbonylation of the phenacetyl radical. Dissociation is initiated at 282 nm in solutions of methanol and cyclohexane a