𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Photoassisted, iron-catalyzed allylic amination of olefins with nitroarenes

✍ Scribed by Radhey S. Srivastava; Manoj Kolel-Veetil; Kenneth M. Nicholas


Book ID
104232349
Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
94 KB
Volume
43
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Photo-induced iron-catalyzed allylic ami
✍ Radhey S. Srivastava πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 104 KB πŸ‘ 1 views

## Abstract Photochemical reactions between unfuctionalized olefins and nitroarenes under CO pressure, catalyzed by [Cp\*Fe(CO)~2~]~2~, form the corresponding allyl amines. The use of mechanistic probes containing 2‐nitrobiphenyl, 2,3‐dimethylbutadiene and pentafluoronitrobenzene suggest that neith

Copper-catalyzed allylic amination of ol
✍ Radhey S Srivastava πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 131 KB

The transition metal catalyzed allylic amination of olefins are studied. A screening of catalysts known for the intermediacy of PhNO in the amination of alkene with phenylhydroxylamine reveals that the hydrated copper salt in conjugation with copper powder as reductant has the best catalytic propert

Cu(I)-catalyzed allylic amination of ole
✍ Gregg A Hogan; August A Gallo; Kenneth M Nicholas; Radhey S Srivastava πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 272 KB

The copper(I) complex [Cu(CH 3 CN) 4 ]PF 6 catalyzes the allylic amination of alkenes by aryl hydroxylamine in fair to moderate yields. Unsymmetrical alkenes react with high regioselectivity with N-functionalization occuring at the less substituted vinylic carbon. Trapping experiments indicate that

Cu(I)-Catalyzed Allylic Amination of Ole
✍ Gregg A. Hogan; August A. Gallo; Kenneth M. Nicholas; Radhey S. Srivastava πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons βš– 136 KB πŸ‘ 2 views