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Cu(I)-Catalyzed Allylic Amination of Olefins.

✍ Scribed by Gregg A. Hogan; August A. Gallo; Kenneth M. Nicholas; Radhey S. Srivastava

Publisher
John Wiley and Sons
Year
2003
Weight
136 KB
Volume
34
Category
Article
ISSN
0931-7597

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## Abstract Photochemical reactions between unfuctionalized olefins and nitroarenes under CO pressure, catalyzed by [Cp\*Fe(CO)~2~]~2~, form the corresponding allyl amines. The use of mechanistic probes containing 2‐nitrobiphenyl, 2,3‐dimethylbutadiene and pentafluoronitrobenzene suggest that neith